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The Art of Science

Saturday, 11 August 2007. What we can do in Asymmetric Organocatalysis except to design catalysts based on the enamine, iminium mechanism or explore the potential of chiral phosphoric acid? The answer might be Cascade Reactions. That is an unexplored field in organocatalysis except some recent papers published by List, Terada and Wang. Early this year, List reported an amazing reaction which combined enamine catalysis, iminium catalysis and Bronsted acid catalysis to form cyclohexylamine. For their devel...

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The Art of Science | angew-jacs.blogspot.com Reviews
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Saturday, 11 August 2007. What we can do in Asymmetric Organocatalysis except to design catalysts based on the enamine, iminium mechanism or explore the potential of chiral phosphoric acid? The answer might be Cascade Reactions. That is an unexplored field in organocatalysis except some recent papers published by List, Terada and Wang. Early this year, List reported an amazing reaction which combined enamine catalysis, iminium catalysis and Bronsted acid catalysis to form cyclohexylamine. For their devel...
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The Art of Science | angew-jacs.blogspot.com Reviews

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Saturday, 11 August 2007. What we can do in Asymmetric Organocatalysis except to design catalysts based on the enamine, iminium mechanism or explore the potential of chiral phosphoric acid? The answer might be Cascade Reactions. That is an unexplored field in organocatalysis except some recent papers published by List, Terada and Wang. Early this year, List reported an amazing reaction which combined enamine catalysis, iminium catalysis and Bronsted acid catalysis to form cyclohexylamine. For their devel...

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The Art of Science: Hydrogen-Mediated C-C Bond Formation

http://angew-jacs.blogspot.com/2007/07/hydrogen-mediated-c-c-bond-formation.html

Sunday, 29 July 2007. Hydrogen-Mediated C-C Bond Formation. In the last group meeting I presented Krische. S work on the hydrogen-mediated C-C bond formation. Krische winned the 2007 Presidential Green Chemistry Challenge Awards. For their development of this methodology. In his 2007 JOC perspective. From a mechanistic point of view, the key for the reductive aldol. Coupling reaction, however, an acid additive is necessary. Based on a computational study. Interestingly, in order to probe the role of acid.

2

The Art of Science: Cascade Reaction

http://angew-jacs.blogspot.com/2007/08/cascade-reaction.html

Saturday, 11 August 2007. What we can do in Asymmetric Organocatalysis except to design catalysts based on the enamine, iminium mechanism or explore the potential of chiral phosphoric acid? The answer might be Cascade Reactions. That is an unexplored field in organocatalysis except some recent papers published by List, Terada and Wang. Early this year, List reported an amazing reaction which combined enamine catalysis, iminium catalysis and Bronsted acid catalysis to form cyclohexylamine.

3

The Art of Science: The essence of chemistry is to create

http://angew-jacs.blogspot.com/2007/02/welcome.html

Wednesday, 7 February 2007. The essence of chemistry is to create. The objective of this blog is to practice my English, keep me learning and share my ideas of chemistry with you. I feel lucky to major in chemistry because chemsitry is the only science subject which create new things. Chemists can have the experience of both Scientists and artists. Chemistry is the art of science. And that is where the name of my blog originated. Hope you will love chemistry too. Posted by Superking at 7:58 am.

4

The Art of Science: Combination of Organometallic Catalysis with Organocatalysis

http://angew-jacs.blogspot.com/2007/07/combination-of-organometallic-catalysis.html

Saturday, 28 July 2007. Combination of Organometallic Catalysis with Organocatalysis. In the current issue of. Utilizing the chiral phosphate anion as a couterion of metal with achiral ligand to induce chirality in organometallic catalysis. The structure of the phosphate anion they used was extensively studied in organocatalysis. The chiral BINOL based phophoric acid was first applied to the asymmetric Mannich type Reaction by. Used them in asymmetric imine reduction. Later they were employed by. In fact...

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The Art of Science

Saturday, 11 August 2007. What we can do in Asymmetric Organocatalysis except to design catalysts based on the enamine, iminium mechanism or explore the potential of chiral phosphoric acid? The answer might be Cascade Reactions. That is an unexplored field in organocatalysis except some recent papers published by List, Terada and Wang. Early this year, List reported an amazing reaction which combined enamine catalysis, iminium catalysis and Bronsted acid catalysis to form cyclohexylamine. For their devel...

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