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Chemical Crystallinity

Organic synthesis and methodology in your (free?) time

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Chemical Crystallinity | chemicalcrystallinity.blogspot.com Reviews
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Organic synthesis and methodology in your (free?) time
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1 chemical crystallinity
2 time
3 features
4 conversion of benzoxazoles
5 scope and conditions
6 posted by
7 crystallinity
8 6 comments
9 labels copper
10 copper catalysis
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chemical crystallinity,time,features,conversion of benzoxazoles,scope and conditions,posted by,crystallinity,6 comments,labels copper,copper catalysis,3 comments,heterocycle,isoindolinone,methodology,org lett,tetrahydropyrazine,phenols from cyclohexanones
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Chemical Crystallinity | chemicalcrystallinity.blogspot.com Reviews

https://chemicalcrystallinity.blogspot.com

Organic synthesis and methodology in your (free?) time

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1

Chemical Crystallinity: September 2009

http://chemicalcrystallinity.blogspot.com/2009_09_01_archive.html

Organic synthesis and methodology in your (free? Sunday, September 27, 2009. Everyone loves neat tricks in synthesis that are not as easy to spot in retrosynthesis as oxidations or reductions. One of these I came across recently is the conversion of furans to tetrahydropyrans, the Achmatowicz reaction, the seminal publication. Of which was in 1971 in Tetrahedron. This reaction was used in a few total syntheses; besides those mentioned in the. Saturday, September 19, 2009. 2 - Crop circles. I need to learn.

2

Chemical Crystallinity: February 2010

http://chemicalcrystallinity.blogspot.com/2010_02_01_archive.html

Organic synthesis and methodology in your (free? Friday, February 26, 2010. Some science for raw foodists. I once lived with a woman who insisted that cooking food broke down the enzymes that we so desperately need from the food. This same roommate also insisted that water kept at room temperature was more "alkaline" than when it was cold. (Though. Is there a temperature dependence constant missing from H. O → H. So, I acknowledge the health benefits of restricting the amount of processed food that one c...

3

Chemical Crystallinity: July 2011

http://chemicalcrystallinity.blogspot.com/2011_07_01_archive.html

Organic synthesis and methodology in your (free? Sunday, July 3, 2011. More copper, please - Part 2 of 4. The next focus on copper-catalyzed reactions. Is direct C-H functionalization. You may be able to tell from past posts that I have a special place in my heart for direct functionalization of C-H bonds. A few recent papers use copper to achieve these kinds of reactions; I'm going over 2 here, bulleting the key points so that there aren't paragraphs upon paragraphs to read. Is 20% really "catalytic"?

4

Chemical Crystallinity: June 2011

http://chemicalcrystallinity.blogspot.com/2011_06_01_archive.html

Organic synthesis and methodology in your (free? Tuesday, June 28, 2011. More copper, please - Part 1 of 4. Lu and coworkers from the Tsinghua University in Shenzhen, China have just published a method. In Org. Lett. To create a combined isoindolinone and 1,4-dihydropyrazine core by copper-catalyzed direct C-H amination, with the goal of creating a new scaffold for potentially biologically active heterocycles. Thursday, June 9, 2011. Paper (doi: 10.1126/science.1204183). Just came out by Shannon Stahl.

5

Chemical Crystallinity: October 2009

http://chemicalcrystallinity.blogspot.com/2009_10_01_archive.html

Organic synthesis and methodology in your (free? Monday, October 26, 2009. Piperazimycin A: A Cyctotoxic Cyclic Hexadepsipetide. Li, Gan, and Ma's recent natural product synthesis of piperazimycin A, the structure. Of which was reported in 2007, in Angewante Chemie. Doi: 10.1002/anie.200904603. Attracted me admittedly because of how gorgeous the 18-membered ring with 6 carbonyls pointed toward each other is - seriously, look at it! Equally toxic reagent, but way cooler. Labels: natural product synthesis.

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chiraljones.wordpress.com chiraljones.wordpress.com

Bigger News | Chiral Jones

https://chiraljones.wordpress.com/2011/01/30/bigger-news

Now with hood space! A little less than a week ago, I received the first acceptance email. After the suspense of a seemingly indefinite wait, and uncertain outcomes, it’s a good, relieving feeling to know I’ll be going. Next year. Now I just need to hear back from everywhere else so I can start planning the North American tour dates…. More importantly, this means I’ll have ample blog/’job’ security for a few more years…. Click to email (Opens in new window). Share on Facebook (Opens in new window). You a...

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Arse, ‘innit? | Chiral Jones

https://chiraljones.wordpress.com/2010/12/08/arse-innit

Now with hood space! Arse, ‘innit? So, as a scientist, here’s my obligatory post regarding the whole “Arsenic Replacing Phosphorus in DNA Backbone” thing. Whether or not it’s true, it really seems as though Wolfe-Simon. Their case, and that’s a problem. (If you want a full breakdown of why the paper is kind of flawed, check out commentaries by Derek Lowe. In response to criticisms, via Nature News. 8220;We are not going to engage in this sort of discussion,” she wrote in an e-mail to Nature. &#...8221; a...

chiraljones.wordpress.com chiraljones.wordpress.com

Big News | Chiral Jones

https://chiraljones.wordpress.com/2011/01/30/big-news

Now with hood space! Chemjobber does it again! Really, he couldn’t be better at what he does – even if he’s not even specifically trying. Way back when he cross posted. Info about my search for grad schools, I got much more than I bargained for.* An editor of C&EN came across my blog, enjoyed the ‘Chiral Jones Experience,’ and contacted me with interest in picking me up over at CENtral Science. So here are the deets:. Yes, I’ll be blogging for C&EN! Incriminating happy hour pics. I’ll let him intro...

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The Chemical blogspace Blog: November 2009

http://chemicalblogspace.blogspot.com/2009_11_01_archive.html

The Chemical blogspace Blog. This blog is used to announce changes in the Chemical Blogspace aggregator. Wednesday, November 25, 2009. A bit more than four hands full of new blogs in the four months since New Blogs #11. Importantly, I have disabled the Accelrys blog in favor if the blogs of its individual contributors, Dana, George, Gerhard, Max, Nancy and Shikna. This is not to boost the number of blogs, but merely reflects that Cb. Dana Honeycutt, Ph.D. George Fitzgerald, PhD. Gerhard Goldbeck-Wood, PhD.

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Science Bloggers! | Mors dei

https://morsdei.wordpress.com/science-bloggers

Below is the ever-growing list of science bloggers, if you know of some not on this list, please, send me an e-mail or leave them in the comments! If you think one of these should not be on this list, tell me why below. It’s a …) Micro World (… after all). A DC Birding Blog. Adventures in Ethics and Science. A Blog Around The Clock. Bug Girl’s Blog. Building Blogs of Science. Greg Laden’s Blog. Living the Scientific Life (Scientist, Interrupted). Observations of a Nerd. The Panda’s Thumb. On Codes and DNA.

chiraljones.wordpress.com chiraljones.wordpress.com

ACD Labs – Check yo’ internets! | Chiral Jones

https://chiraljones.wordpress.com/2011/02/03/acd-labs-check-yo-internets

Now with hood space! ACD Labs – Check yo’ internets! Just a little something I noticed today while trying to look something up about ACD Labs. This is current as of maybe 20 minutes ago:. Sorry it’s a bit small, I suggest you view the full pic. Check out the first and last entries I’ve included from my screen-capture. Have a chuckle at it before ACD gets wise and fixes it. Either someone at ACD labs has a weird sense of humor, is a dissenter, or there’s some skulduggery afoot from a third party. You are ...

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Home, and out of my mind, for the holidays | Chiral Jones

https://chiraljones.wordpress.com/2010/12/31/home-and-out-of-my-mind-for-the-holidays

Now with hood space! Home, and out of my mind, for the holidays. Happy holidays, and a happy New Years (Eve, depending on your timezone) to everybody. As you might expect, I’m in the thick of the holiday slow-down. Granted, many of you will probably be back at the grind some time after the first, but I won’t even be back at school, nor spending any time at “ the altar. Considering I’m at the point where I’ve. No, not my altar, just a particularly clean lookin’ one. Click to email (Opens in new window).

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Chiral Jones is dead. Long live Chiral Jones. | Chiral Jones

https://chiraljones.wordpress.com/2011/02/22/chiral-jones-is-dead-long-live-chiral-jones

Now with hood space! Chiral Jones is dead. Long live Chiral Jones. I was expecting a move to CENtral Science. Finally: Transition States. Blogging will slow down a bit here, but during the beginning, I’ll be sure to cross post (with plenty of links) so you can re-calibrate your RSS antennas. And I might drop the occasional ‘just-for-fun’ post here, too. Thanks for reading this far, everyone. You’re all cordially invited to check out the new blog. Click to email (Opens in new window). From your own site.

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About The Man | Chiral Jones

https://chiraljones.wordpress.com/chiral-jones-the-man

Now with hood space! Chiral Jones is, in my opinion, the coolest pseudonym ever. Like, a Keyser Soze. Of the chemistry world…. If you’ll look to the left, you’ll see my left forearm. Yes, that is an IUPAC tattoo. Yes, I’m well aware of how geeky that is. Yes, I’m ok with that. When not in lab/class, I enjoys cycling, techno beats, and chilling with my cat, Tyler. I don’t know what it is about chemists and the enjoyment of cats, but I believe the correlation is very high. October 6, 2009 at 3:11 am. Addre...

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Chemical Crystallinity

Organic synthesis and methodology in your (free? Sunday, July 3, 2011. More copper, please - Part 2 of 4. The next focus on copper-catalyzed reactions. Is direct C-H functionalization. You may be able to tell from past posts that I have a special place in my heart for direct functionalization of C-H bonds. A few recent papers use copper to achieve these kinds of reactions; I'm going over 2 here, bulleting the key points so that there aren't paragraphs upon paragraphs to read. Is 20% really "catalytic"?

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