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Latest Posts – That Blog by Dylan

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Why two electrons per orbital? – That Blog by Dylan

http://dylan-jayatilaka.net/articles/why-two-electrons-per-orbital

Photo Credit: Rene Magritte - Decalcomania. Bull; pauli principle. Why two electrons per orbital? October 20, 2014. November 04, 2014. Electron are negatively charged and repel each other. How is it possible that within atoms and molecules they suddenly turn schizophrenic and two of them occupy the same orbital? Frankly, this is nuts. I have never encountered a simple, vivid and correct explanation which makes this contradiction acceptable. On the contrary, in basic chemistry, we simply. But how does that.

2

Coupled cluster doubles – That Blog by Dylan

http://dylan-jayatilaka.net/articles/coupled-cluster-doubles

Photo Credit: Samuel Monnier. Bull; doubles wavefunction. June 18, 2014. June 07, 0201. 2014 Dylan Jayatilaka. Powered by Jekyll. Using the So Simple Theme.

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Coupled cluster singles – That Blog by Dylan

http://dylan-jayatilaka.net/articles/coupled-cluster-singles

Photo Credit: Regina Valluzzi - Transition to Chaos. Bull; single excitation. June 17, 2014. June 07, 0201. According to the previous notes the coupled cluster single (CCS) wavefunction has the form. Where the single excitation operator replaces spinorbital ( I ) in determinant ( Phi ) (an occupied) with an orbital ( A ) which does not occur in ( Phi ) (an unoccupied or virtual spoinorbital) i.e. T I A ) is the amplitude associated with the singly excited determinant ( Phi I A ). Using the So Simple Theme.

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Articles – That Blog by Dylan

http://dylan-jayatilaka.net/articles

That Blog by Dylan. Polarizability and hyperpolarizability as Hartree-Fock energy derivatives. November 20, 2014. Molecular properties in the crystalline environment. November 08, 2014. Why two electrons per orbital? October 20, 2014. Designing circulant Hamiltonians for quantum computing. October 17, 2014. Atomic orbitals, Chladni figures, vibrating drums, Faraday waves, Oscillons and the de Broglie-Bohm theory of Quantum Mechanics. October 07, 2014. September 21, 2014. September 20, 2014. June 30, 2014.

5

That Blog by Dylan

http://dylan-jayatilaka.net/about

Photo Credit: Michael Rose. Hi there. I’m Dylan Jayatilaka. I am a Professor and chemist working in theory, computation and diffraction experiments at the University of Western Australia (UWA) in the wonderfully remote city of Perth, on the shores of the Swan River where dolphins frolic. Really. A few elders have taken me under their wing to nurture me. And more than ever, I now get a ton from you out there through the liquid crystal of my misanthropic terminal. I hope to give back some of what I’ve got.

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Latest Posts – That Blog by Dylan

That Blog by Dylan. Polarizability and hyperpolarizability as Hartree-Fock energy derivatives. November 20, 2014. Molecular properties in the crystalline environment. November 08, 2014. Why two electrons per orbital? October 20, 2014. Designing circulant Hamiltonians for quantum computing. October 17, 2014. Atomic orbitals, Chladni figures, vibrating drums, Faraday waves, Oscillons and the de Broglie-Bohm theory of Quantum Mechanics. October 07, 2014. September 21, 2014. September 20, 2014. June 30, 2014.

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