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Sheri Sangji’s death from handling t-butyllithium improperly | my blog
https://puppyreactions.wordpress.com/2012/08/06/bad-chemistry
Sheri Sangji’s death from handling t-butyllithium improperly. August 6, 2012. Well, a verdict has finally been reached (about a week or so ago) on the sentencing of Professor Harran (the PI who Sheri Sangji was working under) and his role in Sangji’s death. But first, here’s a well-spoken blog by Deborah Blum in regards to the whole situation: http:/ www.wired.com/wiredscience/2012/07/sangji-chemistry-death-ucla/. Do you think Dr. Harran should be held responsible (if at all) for Sangji’s death?
Yamaguchi esterification | my blog
https://puppyreactions.wordpress.com/2012/08/05/yamaguchi-esterification
August 5, 2012. I love the name of this one, it reminds me of the Tamagotchi toys I used to play with as a kid (reference for anyone’s personal interest in the game: http:/ en.wikipedia.org/wiki/Tamagotchi. It’s basically the oldest form of Neopets that’s been around since 1996, lol. Anyways, the Yamaguchi esterification is the reaction of an aliphatic carboxylic acid with the Yamaguchi reagent, which is 2,4,6-trichlorobenzoyl chloride, under basic conditions. Here is a mechanistic look at it.
Wittig reaction… | my blog
https://puppyreactions.wordpress.com/2013/01/12/wittig-reaction
January 12, 2013. Key point to take from this reaction: you form. Alkenes, as you have no stabilizing component built into the formed ylide. Oh, and another thing: esters cannot be used in the Wittig reaction, probably because they are less reactive than aldehydes or ketones. For the case of converting esters to alkenes, it’s best to perform the Tebbe-Petasis olefination. If you want to form. Leave a Reply Cancel reply. Enter your comment here. Fill in your details below or click an icon to log in:.
Organometallics | my blog
https://puppyreactions.wordpress.com/2013/03/03/organometallics
March 3, 2013. A timeline of the history of organometallics is shown below (source: Wikipedia):. 1760 Louis Claude Cadet de Gassicourt. Investigates inks based on Cobalt. Salts and isolates Cacodyl. From cobalt mineral containing arsenic. Is the first platinum. 1899 Introduction of Grignard reaction. Organic compounds with metal catalysts. Hydrogenation of fats. Kicks off advances in food industry. For the treatment of syphilis, an early arsenic based organometallic compound. Was awarded the Alfred Stock.
Paulson-Khand reaction | my blog
https://puppyreactions.wordpress.com/2013/03/11/paulson-khand-reaction
March 11, 2013. Although this has been mentioned and presented during one of our group meetings by a third-year graduate student who specializes in studying Paulson-Khand, I never bothered to further investigate the reaction until now. So what exactly is the Paulson-Khand reaction? Leave a Reply Cancel reply. Enter your comment here. Fill in your details below or click an icon to log in:. Address never made public). You are commenting using your WordPress.com account. ( Log Out.
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My ChemDraw hell | Chemical connections
https://stuartcantrill.com/2012/02/22/my-chemdraw-hell
8230;chemistry and other curiosities. My science story (and my Dad). Peer-review polls →. February 22, 2012. Here’s a challenge for you. Draw the structure below in ChemDraw – so that it looks as pretty as it does here* – and let me know how long it took you. If you can do it in under 3 hours, you’re a better ChemDrawerer* than I am. Of course, you probably have much better (and more interesting) things to do with your time. It looks better if you click through to the full size image. Paul over at TotSyn...
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my blog | chemistry literature
March 11, 2013. Although this has been mentioned and presented during one of our group meetings by a third-year graduate student who specializes in studying Paulson-Khand, I never bothered to further investigate the reaction until now.… Continue reading →. March 3, 2013. January 12, 2013. August 15, 2012. Originally posted on Org Prep Daily. Beautiful asymmetric transition metal-catalysed chemistry with phosphine ligands chiral on phosphorus dates back to Knowles and Mislow. But these P-stereogenic h...
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