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RajcaLab Weblog | Organic Radicals and Carbon-Sulfur [n]Helicenes

Organic Radicals and Carbon-Sulfur [n]Helicenes. January 24, 2010. Carbon-Sulfur Bis[7]Helicene: [15]Helicenes with a Missing Link. This is the 5. Post of the helicene series. After asymmetric synthesis of carbon-sulfur [11]helicene, we went back to the drawing board. plugging away at the connection/annelation sequencesthe next challenge was carbon-sulfur [15]helicene. Here is the retrosynthesis. Recently prepared by Nenajdenko and co-workers ( Angew. Chem. Ok, there was no easy way out! Tri-annelation o...

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