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New Remarkably Efficient Ethenolysis Catalysts. April 24, 2015. Marx, V. M. Sullivan, A. H. Melaimi, M. Virgil; S. C. Keitz, B. K. Weinberger, D. S. Bertrand, G. and Grubbs, R. H. Cyclic Alkyl Amino Carbene (CAAC) Ruthenium Complexes as Remarkably Active Catalysts for Ethenolysis. Angew Chem. Int. Ed. Promising results achieved previously with CAAC catalyst 1. In the best performing catalysts 2. Achieved with 99.9% pure ethylene. International Symposium on Olefin Metathesis July 2015. April 21, 2015.

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All Things Metathesis – | allthingsmetathesis.com Reviews
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New Remarkably Efficient Ethenolysis Catalysts. April 24, 2015. Marx, V. M. Sullivan, A. H. Melaimi, M. Virgil; S. C. Keitz, B. K. Weinberger, D. S. Bertrand, G. and Grubbs, R. H. Cyclic Alkyl Amino Carbene (CAAC) Ruthenium Complexes as Remarkably Active Catalysts for Ethenolysis. Angew Chem. Int. Ed. Promising results achieved previously with CAAC catalyst 1. In the best performing catalysts 2. Achieved with 99.9% pure ethylene. International Symposium on Olefin Metathesis July 2015. April 21, 2015.
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All Things Metathesis – | allthingsmetathesis.com Reviews

https://allthingsmetathesis.com

New Remarkably Efficient Ethenolysis Catalysts. April 24, 2015. Marx, V. M. Sullivan, A. H. Melaimi, M. Virgil; S. C. Keitz, B. K. Weinberger, D. S. Bertrand, G. and Grubbs, R. H. Cyclic Alkyl Amino Carbene (CAAC) Ruthenium Complexes as Remarkably Active Catalysts for Ethenolysis. Angew Chem. Int. Ed. Promising results achieved previously with CAAC catalyst 1. In the best performing catalysts 2. Achieved with 99.9% pure ethylene. International Symposium on Olefin Metathesis July 2015. April 21, 2015.

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1

Best Practices

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Storage of Grubbs Catalysts. March 10, 2010. Anhydrous means different things to different people. Seth Herzon I’m sure you’ve seen it written, probably somewhere on this website, that ruthenium olefin metathesis catalysts are stable to air and water. But stability is not a black and white issue. It’s all grey area. So exactly how grey are Grubbs catalysts? For a typical […]. Ring Closing Metathesis Reaction Planning. February 23, 2010. Functional Group Tolerance/Protecting Group Strategy. It’s well know...

2

All Things Metathesis –

http://allthingsmetathesis.com/page/14

Low Polydispersity ROMP Catalyst. October 13, 2009. Although their increased functional-group tolerance has made the ruthenium-based metathesis catalysts extremely attractive for use as polymerization catalysts, these catalysts have typically struggled to match the living polymerizations of the … [Continue reading]. ROMP Catalysts: Key Fundamentals. October 8, 2009. 2nd Generation Grubbs Catalyst. October 7, 2009. Synthesis of Telechelics through Olefin Metathesis. October 6, 2009. The preparation of tel...

3

International Symposium on Olefin Metathesis – July 2015

http://allthingsmetathesis.com/isom-xxi-july-2015

International Symposium on Olefin Metathesis July 2015. April 21, 2015. The 21st International Symposium on Olefin Metathesis and Related Chemistry (ISOM XXI) will be held in Graz, Austria from July 12-16, 2015. ISOM XXI will cover the following topics:. Catalyst development and Organometallic Chemistry of carbenes and carbynes. Application of Olefin Metathesis in Organic and Pharmaceutical Chemistry. Application of Olefin Metathesis in Materials and Polymer Chemistry. Visit the ISOM XXI site. Is intende...

4

New Remarkably Efficient Ethenolysis Catalysts

http://allthingsmetathesis.com/efficient-ethenolysis-catalysts

New Remarkably Efficient Ethenolysis Catalysts. April 24, 2015. Marx, V. M. Sullivan, A. H. Melaimi, M. Virgil; S. C. Keitz, B. K. Weinberger, D. S. Bertrand, G. and Grubbs, R. H. Cyclic Alkyl Amino Carbene (CAAC) Ruthenium Complexes as Remarkably Active Catalysts for Ethenolysis. Angew Chem. Int. Ed. Promising results achieved previously with CAAC catalyst 1. In the best performing catalysts 2. Achieved with 99.9% pure ethylene. Be Sociable, Share! Leave a Reply Cancel reply. Required fields are marked *.

5

All Things Metathesis –

http://allthingsmetathesis.com/page/2

Controlling the Light Path to Metathesis. July 30, 2015. Levin, E. Mavila, S. Eivgi, O. Tzur, E. Lemcoff, N.G. Regioselective Chromatic Orthogonality with Light-Activated Metathesis Catalysts Angew. Chem. Int. Ed. 2015, Advance Article. DOI: 10.1002/anie.201500740 The control of molecular bond … [Continue reading]. Two Reactions for the Price of One Olefin Metathesis Catalyst. June 26, 2015. Ski, C. Samoj? Olefin Metathesis in Self-Healing Materials. May 29, 2015. April 24, 2015. Marx, V. M. Sull...The 2...

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Finding Teaching Skills in Unexpected Places | Cheersical Education

https://graphiteworks.wordpress.com/2015/06/03/finding-teaching-skills-in-unexpected-places

All things chemical education: research, practice, theory, and more. New Vistas in Reaction Kinetics. Finding Teaching Skills in Unexpected Places. Developing Concepts in General Chemistry; Symposium on Chemistry MOOCs. Organic Chemistry Curriculum: A Step in the Right Direction. What Does “Inquiry” Mean? Adventures in the Midwest. Techniques in Learning and Teaching. June 3, 2015. Finding Teaching Skills in Unexpected Places. The other day as I was recording a video. No planes of symmetry at all. Brute ...

metalorganicreactions.blogspot.com metalorganicreactions.blogspot.com

Metal-Mediated Organic Reactions: November 2011

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MMOR is a summary of literature relating to organic reactions that are either mediated or catalyzed by organometallic or Lewis acid catalysts. View my complete profile. Tuesday, November 29, 2011. Reaction Development and Mechanistic Study of a Ruthenium Catalyzed Intramolecular Asymmetric Reductive Amination en Route to the Dual Orexin Inhibitor Suvorexant (MK-4305). J Am Chem. Soc. Org Process Res. Dev. 2011, 15, 367–375 ( DOI:. Subscribe to: Posts (Atom). ACS Organic Division Web Links. Synthetic Natu...

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Metal-Mediated Organic Reactions: May 2007

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MMOR is a summary of literature relating to organic reactions that are either mediated or catalyzed by organometallic or Lewis acid catalysts. View my complete profile. Sunday, May 6, 2007. Rhodium-Catalyzed Asymmetric Synthesis of 3,3-Disubstituted 1-Indanones. Ryo Shintani, Keishi Takatsu, Tamio Hayashi. Angewandte Chemie International Edition. DOI: 10.1002/anie.200700226. The resulting substituted indanones arrive from a tandem Rh-catalyzed C-H functionalization-cyclization sequence. ACS Organic Divis...

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Those hard to find references — B.R.S.M.

http://brsmblog.com/those-hard-to-find-references

Tet Lett. Is other people. Those hard to find references. In a recent group meeting the old Woodward aphorism came out again: "the only model system worth using is the enantiomer", which led to a scrabble afterwards to find. From - or (-)-camphor, for the final sequence they found that it was in fact more efficient to instead use a resolution of the earlier indoline, accomplished by derivatisation with (. Α-phenylethyl isocyanate and separation of the resulting diastereomers. Woodward put it thusly:.

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Jiadifenolide (Part 2: Dalby/Paterson) — B.R.S.M.

http://brsmblog.com/jiadifenolide-paterson-total-synthesis

Pain is temporary, publications are eternal. Jiadifenolide (Part 2: Dalby/Paterson). In the four months I spent not writing this post, the Paterson Dalby synthesis of jiadifenolide was covered over at Synthetic Nature. But as I’d already put a few hours into it I decided to use the Christmas holidays to dust it off and finish it up. Enjoy! Total Synthesis of Jiadifenolide. Angew Chem. Int. Ed. 7286 7289 [ PDF. DOI: 10.1002/anie.201404224. No fancy starting materials here! CBPA to form only the. Selective...

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Maoecrystal V (Part 1: Thomson) — B.R.S.M.

http://brsmblog.com/maoecrystal-v-part-1-thomson

All this happened, more or less. Maoecrystal V (Part 1: Thomson). Enantioselective Total Synthesis of -Maoecrystal V. Regan J. Thompson. J Am Chem. Soc. Maoecrystal V as the advanced nature of its final letter implies is one of a great many unusual terpinoids from the Chinese flowing plant. Maoecrystal V exhibits a heavily modified version of the more common. J Am Chem. Soc. Earlier this month and I’ve now got plenty time to write about both of them, starting with that of the Thomson group in this post.

joshphd.wordpress.com joshphd.wordpress.com

How do people do it? | A PhD's Life

https://joshphd.wordpress.com/2012/02/01/how-do-people-do-it

A PhD's Life. My life as an Assistant Professor…. How do people do it? I suck at it! I truly envy people who have the ability to multitask. I have tried and tried to no avail. It seems that the harder I try to multitask, they more I focus on one task. I desperately need to learn to multitask because it really stinks only being able to focus on one task at a time. 8221; “Is that enough information? 8221; “Can I draw that figure better myself? 8221; The questions go on and on in my mind. Dr Dad, PhD. In th...

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New Contract | A PhD's Life

https://joshphd.wordpress.com/2012/05/02/new-contract-2

A PhD's Life. My life as an Assistant Professor…. MY SEMESTER IS OVER! Not only that, but I gotta very nice 4% pay increase! I honestly cannot say enough about how much I love my job. It is the perfect job for me in every way. It is in the perfect location. It has the perfect balance between teaching and research (for me). I have great colleagues and great bosses. I really plan on staying here as long as they keep me around. Now back to planning out some syntheses! Laquo; Online Exams. Date : May 2, 2012.

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Online Exams | A PhD's Life

https://joshphd.wordpress.com/2012/03/14/online-exams

A PhD's Life. My life as an Assistant Professor…. I know that when I coordinate my course (next Spring) I will be using scantrons for all of my exams! I can’t handle another exam like this morning. After that experience, I can really use a break. Too bad I’m 12-month faculty…no Spring Break for me. However, there is a light at the end of the tunnel. I am going to a week-long conference the last week of this month! Laquo; The Idea Book. Date : March 14, 2012. Leave a Reply Cancel reply. 28 and a PhD.

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All Things Metathesis –

New Remarkably Efficient Ethenolysis Catalysts. April 24, 2015. Marx, V. M. Sullivan, A. H. Melaimi, M. Virgil; S. C. Keitz, B. K. Weinberger, D. S. Bertrand, G. and Grubbs, R. H. Cyclic Alkyl Amino Carbene (CAAC) Ruthenium Complexes as Remarkably Active Catalysts for Ethenolysis. Angew Chem. Int. Ed. Promising results achieved previously with CAAC catalyst 1. In the best performing catalysts 2. Achieved with 99.9% pure ethylene. International Symposium on Olefin Metathesis July 2015. April 21, 2015.

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